Simtec Coatings
2088 2nd St. MATERIAL SAFETY DATA SHEET
Norcoa, CA 92865
Transportation
Emergency
Non-Transportation Emergency
Call Chemtrec: 1-800-424-9300 951-279-7010
1. PRODUCT DESCRIPTION:
Product
..: Thick & Sandable
HD Bondtec Clear
Product #
....: 20x50TS
Chemical Family
..: Polyester Resin
Chemical Name
: Unsaturated Polyester
2. HAZARDOUS INGREDIENTS:
Name/CAS# Exposure limits Concentration
Styrene/
100-42-5 osha: 50.00 PPM Twa 21%
100.00 PPM Stel
acgih: 50.00 PPM Twa
100.00 PPM Stel
3. HAZARDOUS IDENTIFICATION:
Hazardous Overview
Warning! Color: Pinkish tint; Form: Viscous Liquid;
Odor: Negligible; May cause respirator tract irritation; Inhalation may cause nausea or
dizziness; May cause eye
irritation; May be harmful if
swallowed; Irritating gases/fumes may be
given off during burning or thermal decomposition.
Potential Health
Effects:
Route of entry
:
Inhalation; skin contact; skin absorption; eye contact
Human Effects and
Symptoms of Overexposure:
Air monitoring
conducted during the curing of this product has shown that acrolein
and acetaldehyde vapors can be generated; if curing occurs in an unventilated
area exposure limit for acrolein could be
exceeded. The following health effects
include signs and symptoms associated with overexposure to acrolein
and acetaldehyde.
Acute Inhalation
..: Acrolein vapors cause severe respiratory and eye
irritation. Symptoms of overexposure
include lacrimation, a burning sensation in the
throat, cough, chest discomfort and cyanosis (bluish discoloration of earlobes,
lips and fingernails due to lack of oxygen in the blood). The tlv is designed
to minimize irritation. Acetaldehyde
vapors cause respiratory and eye irritation.
The irritant effects include cough and burning sensation in the nose,
throat and eyes. High concentrations can
cause central system depression.
Chronic Inhalation
.: None known.
Acute Skin Contact
: Based on animal testing (see animal toxicity
section), this product is not expected to be a skin irritant.
Chronic Skin
Contact
: None known.
Acute Eye
Contact
.: Based on animal testing,
eye contact with liquid, aerosols and vapors of this product are not expected
to cause eye irritation. However, eye
contact with acrolein and acetaldehyde vapors (which
can be generated during curing) at concentrations above their respective tlvs can cause redness, tearing and swelling of the eyes.
Chronic Eye
Contact
.: None known.
Acute Ingestion
..: Can cause
irritation in the mouth, stomach tissue and digestive tract.
Chronic Ingestion
..: None known.
Carcinogenicity
NTP
.: Not listed.
IRAC
..: Not
listed.
OSHA
.: Not regulated.
MEDICAL CONDITIONS
Aggravated by
Exposure
..:
Respiratory disorders may be aggravated by exposure to acrolein and acetaldehyde vapors.
Exposure Limits
: Not established for product as a whole, refer to section 2
for exposure limits of hazardous constituents.
FIRST AID MEASURES:
First Aid For Eyes
.:
Flush with clean, lukewarm water (low pressure) for at least 15 minutes
occasionally lifting eyelids. Obtain
medical attention.
First Aid For Skin
.:
Remove contaminated clothing.
First Aid For Inhalation
..: Move to an area
free from risk of further exposure.
Administer artificial respiration or oxygen if needed. Obtain medical attention immediately.
First Aid For Ingestion
:
DO NOT INDUCE VOMITING. DO NOT
GIVE ANYTHING BY MOUTH TO AN UNCONCIOUS PERSON.
Consult physician.
FIRE FIGHTING
MEASURES:
Flash
Point
: 98 F (36.6 C) Pensky-Martens Closed cup (astm D-93)
Flammable
Limits
: (UEL)(%): 6.1 Styrene
(LEL) (%): 1.1 Styrene
Extinguishing Media
..: Dry chemical;
Carbon dioxide; Foam; Water.
Special Fire Fighting
Procedures: Full emergency equipment
with self-contained breathing apparatus should be worn by firefighters. During a fire thermal decomposition and combustion
may generate irritating and toxic gases and aerosols.
Unusual
Fire/Explosion Hazards: Closed container
may explode when exposed to extreme heat.
Use cold water spray to cool fire-exposed containers to minimize risk of
rupture.
6. ACCIDENTAL RELEASE MEASURES:
Spill or Leak
Procedures
: Evacuate non-essential
personnel. Remove all sources of
ignition and ventilate the area. Dike or
impound spilled material and control further spillage if feasible. Notify appropriate authorities if necessary. Cover spill with sawdust, vermiculite,
Fullers earth or other absorbent material.
Collect material and place in a clean empty drum for disposal. Utilize recommended protective
equipment.
7. HANDING & STORAGE:
Storage Temperature
(min/max.): 41 F (5 C) / 68 F (20 C)
Shelf
Life
..:
Special
Sensitivity
: Heat, light,
moisture.
Handling/Storage
Precautions
: Stored in closed
containers and in the dark at temperatures less than 68 F (20 C). If organic peroxide curing agents are used, mixing with pure
accelerators can cause decomposition with explosive force. One material must be thoroughly dispersed in
the resin before the second is added.
PERSONAL PROTECTION:
Eye-protection
Requirements
: Splash goggles, safety
glasses or face shield. Contact lenses
should not be worn.
Skin Protection
Requirements
..:
Permeation resistant gloves.
Ventilation/Respiratory
Requirement: Exhaust ventilation
sufficient to keep the airborne concentrations of acrolein
and acetaldehyde below the appropriate TLVs during curing of coating system must be utilized. Exhaust air may need to be cleaned by
scrubbers & filters to reduce environmental contamination. Curing ovens must be ventilated to prevent
off-gases from entering the workplace.
PHYSICAL AND CHEMICAL
PROPERTIES:
Physical
Form
.: Liquid
Color
: Colorless to Pink
Odor
.: Of Solvent
Boiling Point
.: Styrene: 293 F (145 C)
Heat Distortion Temperature
..: 280 F
Melting/Freezing
Point
.: Styrene: -23 F (-30.5 C)
Solubility in
Water
.: Insoluble
Specific Gravity
.: 1.12 at 68 F (20 C)
Bulk Density
.: Approx.
8.77 LB/gal Clear
% Volatile By Weight
..: 25 %
Vapor Pressure
..: Less
than 7.5 mm Hg @ 68 F (20 C)
Vapor
Density
.: 3.59 (Styrene) (Air = 1)
VOC
: 299.6 grams Per Gallon or 79 Grams Per Liter
STABILITY AND
REACTIVITY:
Stability
..: Stable
when stored in dark at temperatures below 68 F (20 C).
Hazardous
Polymerization
: May occur; If product is not
stored in dark at temperatures below 68 F (20 C), polymerization may occur.
Incompatibilities
: Aliphatic hydrocarbons.
Instability
Conditions
: None known.
Decomposition
Products
: By fire:
CO2, CO. During curing process: Acrolein,
Acetaldehyde.
TOXICOLOGICAL
INFORMATION:
Acute Toxicity
Oral LD50
: Greater than 5000 mg/kg (rat)
Eye Effects
:
Non-irritant (rabbit)
Skin Effects
: Slightly Irritating, 24h
(rabbit)
ECOLOGICAL INFORMATION:
No Ecological
Information Available
DISPOSAL
CONSIDERATIONS:
Waste Disposal
Method
: Waste must be disposed of in
accordance with Federal, State and local environmental control
regulations. Incineration is the
preferred method. Empty containers must
be handled with care due to product residue.
Decontaminate containers prior to disposal.
TRANSPORTATION
INFORMATION:
Technical Shipping
Name
.: Resin Solution
Freight Class
..: 55
Hazard Class Division
..: 3
UN #
..: UN1866
Subsidiary Risk
..: None
Packing Group
..: III
Hazard Label
..: Flammable Liquid
Radioactive
..: Non-radioactive
15. REGULATORY INFORMATION:
The following chemicals are
specifically listed by individual states; other product specific health and
safety data in other sections of the MSDS may also be applicable for state
requirements. For details on your
regulatory requirements you should contact the appropriate agency in your
state.
Name/cas #
Concentration State Code
Styrene /
100-42-5
24% PA1,MA,NJ1
Acetaldehyde /
75-07-0
*% CA
Unsaturated Polyester
Resin 65-75% PA3
Ester
1- 10 % PA3
CA =
MA =
NJ1 =
PA1 =
PA3 =
OTHER INFORMATION:
None
This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Simtec. The data on this sheet relates only to the material specified herein. Simtec assumes no legal responsibility for use or reliance upon these data.
Effective Date: 1-27-2010 Approved By Mike DeVries