Simtec Coatings
2088 2nd Street MATERIAL SAFETY DATA SHEET
Norco, CA 92860
Transportation
Emergency
Non-Transportation Emergency
Call Chemtrec: 1-800-424-9300 951-279-7010
1. PRODUCT
DESCRIPTION:
Product
..: UV Cure Pore Filler
Product #
..: 59x1
Chemical Family
..: Polyester Acrylate
Chemical Name
:
2. HAZARDOUS INGREDIENTS:
Name/CAS# Exposure limits Concentration
Ethylbenzene Cas#
100-41-4 osha: 100 PPM Twa .01 to .07%
150. PPM Stel
Acgih
100 PPM Twa
150 PPM Stel
Silica Cas#
7631-86-9
2% to 6%
PhotoInitiatior
1%
to 4%
3. HAZARDOUS IDENTIFICATION:
Hazardous Overview
Warning! Odor:
Negligible; May cause respirator tract irritation; Inhalation may cause nausea or dizziness; May cause eye irritation; May be harmful if swallowed; Irritating gases/fumes may be given off
during burning or thermal decomposition.
Potential Health
Effects:
Route of entry
: Inhalation; skin contact; skin
absorption; eye contact
Human Effects and
Symptoms of Overexposure:
Air monitoring conducted
during the curing of this product has shown that acrolein
and acetaldehyde vapors can be generated; if curing occurs in an unventilated
area exposure limit for acrolein could be
exceeded. The following health effects
include signs and symptoms associated with overexposure to acrolein
and acetaldehyde.
Acute Inhalation
..: Symptoms of overexposure include lacrimation, a burning sensation in the throat, cough,
chest discomfort and cyanosis (bluish discoloration of earlobes, lips and
fingernails due to lack of oxygen in the blood). The tlv is designed
to minimize irritation. The irritant
effects include cough and burning sensation in the nose, throat and eyes. High concentrations can cause central system
depression.
Chronic Inhalation
.: None known.
Acute Skin Contact
: Based on animal testing (see animal toxicity
section), this product is not expected to be a skin irritant.
Chronic Skin
Contact
: None known.
Acute Eye Contact
.: Based on animal testing, eye contact with
liquid, aerosols and vapors of this product are not expected to cause eye
irritation. .
Chronic Eye
Contact
.: None known.
Acute Ingestion
..: Can cause irritation in the mouth, stomach
tissue and digestive tract.
Chronic Ingestion
..: None known.
Carcinogenicity
NTP
.: Not listed.
IRAC
..: Not listed.
OSHA
.: Not regulated.
MEDICAL CONDITIONS
Aggravated by
Exposure
..: Respiratory disorders
may be aggravated by exposure to acrolein and
acetaldehyde vapors.
Exposure Limits
: Not established for product as a whole, refer to section 2 for exposure limits of
hazardous constituents.
4. FIRST AID MEASURES:
First Aid For Eyes
.: Flush with clean, lukewarm water (low
pressure) for at least 15 minutes occasionally lifting eyelids. Obtain medical attention.
First Aid For Skin
.: Remove contaminated clothing.
First Aid For
Inhalation
..: Move to an area free
from risk of further exposure.
Administer artificial respiration or oxygen if needed. Obtain medical attention immediately.
First Aid For
Ingestion
: DO NOT INDUCE
VOMITING. DO NOT GIVE ANYTHING BY MOUTH
TO AN UNCONCIOUS PERSON. Consult
physician.
5. FIRE FIGHTING MEASURES:
Flash
Point
: 200F (25 C) Tag closed
cup
Extinguishing Media
..: Dry chemical; Carbon dioxide;
Foam; Water.
Special Fire Fighting
Procedures: Full emergency equipment
with self-contained breathing apparatus should be worn by firefighters. During a fire thermal decomposition and
combustion may generate irritating and toxic gases and aerosols.
Unusual
Fire/Explosion Hazards: Closed container
may explode when exposed to extreme heat.
Use cold water spray to cool fire-exposed containers to minimize risk of
rupture.
6. ACCIDENTAL RELEASE MEASURES:
Spill or Leak
Procedures
: Evacuate non-essential
personnel. Remove all sources of
ignition and ventilate the area. Dike or
impound spilled material and control further spillage if feasible.
Notify appropriate authorities if necessary. Cover spill with sawdust, vermiculite,
Fullers earth or other absorbent material.
Collect material and place in a clean empty drum for disposal. Utilize recommended protective
equipment.
7. HANDING & STORAGE:
Storage Temperature
(min/max.): 41 F (5 C) / 68 F (20 C)
Shelf
Life
..: 6 Months
Special
Sensitivity
: Heat, light,
moisture.
Handling/Storage
Precautions
: Stored in closed
containers and in the dark at temperatures less than 68 F (20 C). If organic peroxide curing agents are
used, mixing with pure accelerators can
cause decomposition with explosive force.
One material must be thoroughly dispersed in the resin before the second
is added.
8. PERSONAL PROTECTION:
Eye-protection
Requirements
: Splash goggles, safety
glasses or face shield. Contact lenses
should not be worn.
Skin Protection
Requirements
..: Permeation resistant
gloves.
Ventilation/Respiratory
Requirement: Exhaust ventilation
sufficient to keep the airborne concentrations of acrolein
and acetaldehyde below the appropriate TLVs during curing of coating system must be utilized. Exhaust air may need to be cleaned by
scrubbers & filters to reduce environmental contamination. Curing ovens must be ventilated to prevent
off-gases from entering the workplace.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Physical
Form
.: Paste
Color
: Clear
Odor
.: OF Resin
Boiling Point
.:
Styrene:130 F
Melting/Freezing
Point
.: Styrene: -23 F (-30.5 C)
Solubility in
Water
.: Insoluble
Specific Gravity
.: 1.4 at 68 F (20 C)
Bulk Density
.:
8.8 lbs per gallon
% Volatile By Weight
..: 1%
Vapor
Pressure
..: Less than 7.5 mm Hg
@ 68 F (20 C)
Vapor
Density
.: 3.59 (Styrene) (Air = 1)
VOC
: Not applicable
10. STABILITY AND REACTIVITY:
Stability
..: Stable when stored in dark at temperatures
below 68 F (20 C).
Hazardous Polymerization
: May occur;
If product is not stored in dark at temperatures below 68 F (20 C),
polymerization may occur.
Incompatibilities
: Aliphatic hydrocarbons.
Instability
Conditions
: None known.
Decomposition
Products
: By fire:
CO2, CO. During curing
process: Acrolein,
Acetaldehyde.
11. TOXICOLOGICAL INFORMATION:
Acute Toxicity
Oral LD50
: Greater than 5000 mg/kg (rat)
Eye Effects
:
Non-irritant (rabbit)
Skin Effects
:
Slightly Irritating, 24h (rabbit)
12. ECOLOGICAL INFORMATION:
No Ecological Information Available
13. DISPOSAL CONSIDERATIONS:
Waste Disposal
Method
: Waste must be disposed of in
accordance with Federal, State and local environmental control
regulations. Incineration is the
preferred method. Empty containers must
be handled with care due to product residue.
Decontaminate containers prior to disposal.
14. TRANSPORTATION INFORMATION:
Not Regulated
15. REGULATORY INFORMATION:
None
.
16. OTHER INFORMATION: None
This
information is furnished without warranty, expressed or implied, except that it
is accurate to the best knowledge of Simtec.
The data on this sheet relates only to the material specified
herein. Simtec assumes no legal
responsibility for use or reliance upon these data.
Effective Date:
01-01-2011
Approved By: Mike De Vries
Simtec
~ 2088 2nd Street
Norco, CA 92860